BIS{4-BROMO-2-[(2-HYDROXYETHYL)IMINOMETHYL]PHENOLATO-κ3O,N,O′}CADMIUM

Bis{4-bromo-2-[(2-hydroxyethyl)iminomethyl]phenolato-κ3O,N,O′}cadmium

Bis{4-bromo-2-[(2-hydroxyethyl)iminomethyl]phenolato-κ3O,N,O′}cadmium

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The centrosymmetric title compound, [Cd(C9H9BrNO2)2], was obtained by the Golf Glove reaction of 5-bromosalicylaldehyde, 2-aminoethanol and cadmium nitrate in ethanol.The Cd atom, located on an inversion centre, is hexacoordinated by two Schiff base ligands in an octahedral coordination through the phenolate O atom, the imine N atom and the hydroxy O atoms.In the Wet Mops crystal, molecules are linked through intermolecular O—H.O hydrogen bonds, forming chains along the b axis.

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